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9.5. Option - Polymers : 4. Synthetic
polymers remain in the environment for a long time
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Syllabus
reference (October 2002 version) |
| 4. As synthetic polymers are
not natural substances they do not decompose but remain in the environment
for a long time
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Students learn to:
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Students:
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Extract from Senior Science Stage 6
© Board of Studies, NSW.
[Edit 12 May 11]
Prior learning: ScienceStages 4–5
Background information: Unlike their
natural counterparts, most synthetic polymers are not biodegradable (i.e. decomposed
by micro-organisms). They do not rot, nor are they broken down by the action
of weather. In some cases this can be an advantage, but it can cause problems
The recycling of synthetic polymers can
save energy, raw materials and prevent damage to the environment.
identify
that micro-organisms are part of the natural environment and their role
as decomposers is vital in the ecosystem, with particular emphasis on the
recycling of matter in ecosystems
- A micro-organism (microbe) is a very small (microscopic)
living creature.
Examples of micro-organisms are fungi (moulds and yeasts) and bacteria.
- The environment is the conditions in which a plant
or animal lives.
- An ecosystem is a group of living things, together
with their environment.
- A decomposer is an organism that feeds on and breaks
down organic compounds, which are then returned to ecosystems to be re-used.
- Matter, including nutrients are recycled with the
help of micro-organisms.
The major nutrient cycles are those involving
oxygen, carbon, nitrogen and water.

apply
the term biodegradability to those substances which can be decomposed by
micro-organisms.
- A substance that is biodegradable can be broken down
by the action of living things such as micro-organisms.

gather,
process and
analyse secondary information, to assess the viability of
recycling plastics including those with additives such as
– stabilisers
– plasticisers
– fire-retardants
- A good way to analyse information is to structure
the information in a table. Well-designed tables assist you to identify trends,
patterns and relationships. Try using a table to analyse the information from
the notes provided below.
Backgroud information
Organisations may not recycle plastics
if it is not a viable (eg financially worthwhile) process.
The cost of recycling the plastic
needs to be compared with cost of manufacturing new plastic.
The quality of the recycled plastic
may not be high.
Environmental considerations need
to be taken into account – ie recycling may be “better”
than landfill or other methods of disposal.
Some objects may be made of a mixture
of plastics (and other materials) and be difficult to recycle.
Plastics that are not “pure”,
but contain additives may be more difficult to recycle.
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- Stabilisers are added to plastics to help them keep
their original properties.
- Plasticisers are added to plastics to make them more
flexible.
- Fire retardants are added to decrease the flammability
of plastics.
gather
and process information from
secondary sources to present local government regulations on recycling of plastics
in the local area
- To gather this information ring your local
council and ask for the Health and Environment section. Ask if they have some
information to send you. If they do not , arrange to have an interview with
the appropriate person.
- When you have enough information, process it
by arranging it in a logical order. You might draw up a table with the different
grades of plastic in the left hand column and then record how that grade is
treated by your council. Most councils will recycle plastic containers with
the numbers 1,2 and 3 in the recycle triangle. Plastic bags are not taken
by curbside recycling but some supermarkets will take them.
| Background information
Local governments have a responsibility
to collect and dispose of waste.
Many local authorities have a policy
of recycling materials including plastics.
Many local authorities supply (and
collect) containers specifically for recyclable materials.
Councils may consider methods to
encourage people to recycle, such as charging extra if waste is over
a particular weight.
There may be different regulations
for domestic and industrial waste. |

compare
the relative biodegradability of natural and synthetic polymers and assess
the impact of synthetic polymers in aquatic and terrestrial environments
- Because synthetic polymers are durable, easily shaped
and coloured, they have been widely used for packaging. Disposal of this plastic
packaging (and other plastic products) can cause problems as they don’t
break down easily.
- Natural polymers include such materials as cotton,
wool, cellulose and silk.
Natural polymers have substances such as amino acids and glucose as their
monomers. Because of their chemical make-up, many natural polymers are biodegradable.
- Aquatic environments are those involving water, eg
ponds, rivers and dams.
Terrestrial environments are those in or on the ground. Organic matter needs
moisture, warmth and air to be decomposed.
- Plastics are not broken down quickly by weather, i.e.
heat, cold, wind or rain.
Plastics are not digestible by living creatures.
- Plastic that is thrown away is often buried as landfill.
Burying is not a particularly good solution as plastics do not decompose quickly
and landfill takes up large areas of land. However if plastic is made from
biodegradable material the problem of filling up landfill and contaminating
the soil will not occur. Some information on this can be found at Reactive
Extrusion Processing and Extrusion Polymerization
Chemical Engineering
and Materials Science, Michigan State University, scroll down to Biobased
Thermoplastics and Thermoset composites.
- Some plastics contain substances that may cause damage
as these plastics eventually break down. Some materials, lost or thrown away,
such as polythene bags, nylon fishing lines or nets, can remain as a danger
to wildlife for many years, especially those in water bodies such as rivers
and oceans. Dangerous
Debris and What YOU can do about it
See the sea.org, Salinas, California,
USA

gather,
process, analyse
and present information, to perform
a first-hand investigation to determine the amount of plastic material that
is thrown out per day at school or at home.
- To gather information you will need to look
in the bins at school or at home.
- At school, bins to look in include bins in classrooms,
playgrounds and near canteen facilities. Before you start looking make sure
you have strong plastic gloves and keep an eye out for anything sharp that
may cut you.
- Tip the contents on a plastic sheet and then separate
the plastic from the other rubbish.
- Process the information by recording it in
a table. The headings could be:
Source, Type of plastic, Amount, Recyclable.
- Analyse the information in the table.
- Investigations should take place over several days
so as to obtain reliable results.
The amount of plastic could be measured by number of items, volume or weight.
- Present the information in table form, pie
charts (sector graphs) column graphs (bar charts) or histograms.
- Issues that could be raised include:
- what types of items are most common
- were there any differences between households?
- what were the differences between school and home?
- could some of the plastic items be recycled?

gather
and process first-hand information and information from secondary
sources to describe the coding system developed by industry to aid
the identification and recycling of plastics
- Before plastics can be recycled they have to be identified
and sorted.
- There are so many plastics in common use that consumers
are unlikely to recognise them all.
- Plastics manufacturers have come up with a code.
- The plastic item is stamped with a number from one
to seven within a triangle.
- Collect a range of plastic items and identify them
using the coding system described.

- Look in the library or on the internet to find more
information about coding and recycling. Some questions to answer might be:
- Has this code only been developed for Australia or
are the symbols international?
- Which industry developed the code, the packaging or
recycling industry? Are they different?
- What is the significance of this code to the recycling
industry? Eg. Does it make recycling easier or save money?
discuss
some of the issues involved in recycling plastic materials, downcycling and
the uses of recycled plastics
- The use of plastics worldwide has grown from about
5 million tonnes in the 1950's to around 100 million tonnes today due to their
being lightweight, versatile, inexpensive and durable.
- There are hundreds of different varieties of plastics
and all types are recyclable but only types 1 and 2 in the table above are
currently recycled by kerbside collections carried out by most local councils,
with some councils collecting number 3.
- As more recycled plastic is used so more will be required.
Some current uses of recycled plastics are:
- wheelie bins
- outdoor furniture
- compost bins
- timber substitute planking used in jetties and walking
tracks
- pipes
- pots for plants.
- However these products have to have some new plastic material
in them. A common mix is 75% new and 25% recycled.